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991.
Xiaode Guo Haiyong Cui Fengsheng Li Yi Wang 《Journal of Thermal Analysis and Calorimetry》2013,112(3):1369-1375
As an active catalyst to promote thermolysis of ammonium perchlorate (AP), potassium lead hexanitrocobaltate(II) complex (K2Pb[Co(NO2)6]) was synthesized by the direct deposition method and inverse microemulsion method. Its submicron, size, cube morphology, and crystal structure were investigated by SEM, TEM, and XRD analysis, respectively. Thermal decomposition of K2Pb[Co(NO2)6] was studied by the TG/DSC-IR online system and XRD analysis. The catalyst was decomposed at about 300 °C; its gaseous products were NO2, NO, and N2O and its solid products were Pb3O4, Co3O4, PbO, CoO, and KNO2. Because thermal decomposition of the catalyst was synchronous with low temperature decomposition of AP, thermolysis of AP was promoted remarkably. In particular, the gaseous products (NO x ) could directly oxidize the absorbed NH3. As a result, compared to the data of pure AP, the integral heat of AP added 3.0 wt% of the catalyst multiplied by 280 %, the maximum rate of heat release increased by 634 %. The decomposition of catalyzed AP ended at about 317 °C, at which only less than 30 % of pure AP decomposed. 相似文献
992.
Jiaxi Guo Purnatosh Saha Junfeng Liang Mrinal Saha Brian P. Grady 《Journal of Thermal Analysis and Calorimetry》2013,113(2):467-474
Silica has been non-covalently coated on multi-walled carbon nanotubes (MWCNTs) using the sol–gel chemistry, where tetraethoxy silane (TEOS) was used to form an inorganic silica layer immediately next to surface of MWCNTs and octyl triethoxy silane was coated over the TEOS. Transmission electron microscopy (TEM) measurements show that the diameter of MWCNTs increases with increasing the number of coating layer, indicating that the silica has been coated on MWCNTs. Quantitative analysis from thermogravimetric analysis (TG) also indicates that the inorganic and organic silica has been successfully coated on MWCNTs. Further, quantitative analysis found that the amount of silica measured by TG agrees well with the increase of thickness of coated MWCNTs obtained from TEM, indicating that little or no free silica exists in the system. The thermal conductivity of epoxy/MWCNTs composite was studied and the results show that the thermal conductivity of the composite is improved by coating MWCNTs in this manner and increases with increasing the number of coatings. 相似文献
993.
Yang Guo Wei Zhang Xing Zhou Tong Bao 《Journal of Thermal Analysis and Calorimetry》2013,113(2):787-791
Boron was chosen as fuel owing to its excellent thermodynamic values for combustion. The difficulty of the boron in combustion is the formation of a surface oxide layer, which postpones the combustion process, reducing the performance of the rocket engine. In this paper, magnesium boride was sintered as high-energy fuel as a substitute for boron. The combustion heat and efficiency of magnesium boride and boron were determined using oxygen bomb calorimeter. The combustion characteristics of magnesium boride were investigated by thermal analysis, chemical analysis, XRD, and EDS. Results show that the combustion performance of magnesium boride are better than that of amorphous boron in oxygenated environments. The evaporation of magnesium in magnesium boride combustion process prevent the formation of a closed oxide layer, leading to higher combustion efficiency. 相似文献
994.
Tingting Li Guangwen Yang Jing Wang Yuanyuan Zhou Heyou Han 《Journal of Solid State Electrochemistry》2013,17(10):2651-2660
Recently, tremendous research efforts have been concentrated on developing high-performance electrode materials to meet the ever-increasing energy and power demands in supercapacitors. Herein, we presented a high-capacity supercapacitor material based on nitrogen-enriched hierarchical porous carbons (NHPCs) synthesized by the carbonization of melamine formaldehyde resins using eco-friendly and inexpensive nano-CaCO3 as template. The effects of carbonization temperature and template content on the porous structure and electrochemical characteristics were compared and discussed in detail. The prepared NHPCs possessed large surface area up to 834 m2 g?1 and high nitrogen content up to 20.94 wt %. As electrode material for supercapacitors, NHPCs exhibited superior electrochemical performances with high specific capacitance (190 F g?1 at 20 A g?1), outstanding rate capability (80 %), and excellent cycling stability (over 2,000 cycles at 5 A g?1) in 1 M sulfuric acid media. The excellent electrochemical performances are due to the synergic effects of unique hierarchical porous microstructure, abundant nitrogen and oxygen functionalities, as well as high degree of graphitization framework. 相似文献
995.
Lan Li Long-Yan Li Xiao-Dong Guo Ben-He Zhong Yan-Xiao Chen Yan Tang 《Journal of Solid State Electrochemistry》2013,17(1):115-119
In this paper, porous carbon was synthesized by an activation method, with phenolic resin as carbon source and nanometer calcium carbonate as activating agent. Sulfur–porous carbon composite material was prepared by thermally treating a mixture of sublimed sulfur and porous carbon. Morphology and electrochemical performance of the carbon and sulfur–carbon composite cathode were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), electrochemical impedance spectra (EIS), and galvanostatic charge–discharge test. The composite containing 39 wt.% sulfur obtained an initial discharge capacity of about 1,130 mA?h g?1 under the current density of 80 mA?g?1 and presented a long electrochemical stability up to 100 cycles. 相似文献
996.
Comparative investigations of LiVPO4F/C and Li3V2(PO4)3/C synthesized in similar soft chemical route
Jiexi Wang Zhixing Wang Xinhai Li Huajun Guo Wei Xiao Silin Huang Zhenjiang He 《Journal of Solid State Electrochemistry》2013,17(1):1-8
Triclinic LiVPO4F and monoclinic Li3V2(PO4)3 are synthesized through a soft chemical process with mechanical activation assist, followed by annealing. In this process, ascorbic acid is used as reducing agent as well as carbon source. The as-prepared samples are coated with amorphous carbon. XPS analysis results show the expected valency states of ions in LiVPO4F and Li3V2(PO4)3. The electrochemical properties of the prepared LiVPO4F/C and Li3V2(PO4)3/C cathodes are evaluated. The as-prepared LiVPO4F/C cathode shows an initial discharge specific capacity of 140?±?3 mAh?g?1 at 30 mA?g?1 in the voltage range of 3.0~4.4 V, compared with that of 138?±?3 mAh?g?1 possessed by Li3V2(PO4)3/C. Both samples exhibit good cycle performance at different current densities. The capacity delivered by LiVPO4F remains 95.5 and 91.7 % of its initial discharge capacity after 50 cycles at 150 and 750 mA?g?1, respectively, while 97.4 and 90.6 % for Li3V2(PO4)3/C. But the rate capability of LiVPO4F/C is not so good compared with as-prepared Li3V2(PO4)3/C. 相似文献
997.
998.
Yan Li Dr. Kazuki Fukushima Dr. Daniel J. Coady Dr. Amanda C. Engler Dr. Shaoqiong Liu Yuan Huang Dr. John S. Cho Dr. Yi Guo Dr. Lloyd S. Miller Dr. Jeremy P. K. Tan Dr. Pui Lai Rachel Ee Dr. Weimin Fan Prof. Yi Yan Yang Dr. James L. Hedrick 《Angewandte Chemie (International ed. in English)》2013,52(2):674-678
999.
Dr. Shaojun Guo Sen Zhang Prof. Shouheng Sun 《Angewandte Chemie (International ed. in English)》2013,52(33):8526-8544
Advances in chemical syntheses have led to the formation of various kinds of nanoparticles (NPs) with more rational control of size, shape, composition, structure and catalysis. This review highlights recent efforts in the development of Pt and non‐Pt based NPs into advanced nanocatalysts for efficient oxygen reduction reaction (ORR) under fuel‐cell reaction conditions. It first outlines the shape controlled synthesis of Pt NPs and their shape‐dependent ORR. Then it summarizes the studies of alloy and core–shell NPs with controlled electronic (alloying) and strain (geometric) effects for tuning ORR catalysis. It further provides a brief overview of ORR catalytic enhancement with Pt‐based NPs supported on graphene and coated with an ionic liquid. The review finally introduces some non‐Pt NPs as a new generation of catalysts for ORR. The reported new syntheses with NP parameter‐tuning capability should pave the way for future development of highly efficient catalysts for applications in fuel cells, metal‐air batteries, and even in other important chemical reactions. 相似文献
1000.
Dr. Kazuhiko Amakawa Dr. Lili Sun Dr. Chunsheng Guo Dr. Michael Hävecker Pierre Kube Prof. Dr. Israel E. Wachs Soe Lwin Prof. Dr. Anatoly I. Frenkel Dr. Anitha Patlolla Prof. Dr. Klaus Hermann Prof. Dr. Robert Schlögl Dr. Annette Trunschke 《Angewandte Chemie (International ed. in English)》2013,52(51):13553-13557
Highly dispersed molybdenum oxide supported on mesoporous silica SBA‐15 has been prepared by anion exchange resulting in a series of catalysts with changing Mo densities (0.2–2.5 Mo atoms nm?2). X‐ray absorption, UV/Vis, Raman, and IR spectroscopy indicate that doubly anchored tetrahedral dioxo MoO4 units are the major surface species at all loadings. Higher reducibility at loadings close to the monolayer measured by temperature‐programmed reduction and a steep increase in the catalytic activity observed in metathesis of propene and oxidative dehydrogenation of propane at 8 % of Mo loading are attributed to frustration of Mo oxide surface species and lateral interactions. Based on DFT calculations, NEXAFS spectra at the O‐K‐edge at high Mo loadings are explained by distorted MoO4 complexes. Limited availability of anchor silanol groups at high loadings forces the MoO4 groups to form more strained configurations. The occurrence of strain is linked to the increase in reactivity. 相似文献